Long-term hydrology and aquatic biogeochemistry data from H. J. Andrews Experimental Forest,Cascade Mountains,Oregon     

Sherri L. Johnson  Don Henshaw  Greg Downing  Steve Wondzell  Mark Schulze  Adam Kennedy  Greg Cohn  Stephanie A. Schmidt  Julia A. Jones 《水文研究》2021,35(5):e14187

The H. J. Andrews Experimental Forest (HJA) encompasses the 6400 ha Lookout Creek watershed in western Oregon, USA. Hydrologic, chemistry and precipitation data have been collected, curated, and archived for up to 70 years. The HJA was established in 1948 to study the effects of harvest of old-growth conifer forest and logging-road construction on water quality, quantity and vegetation succession. Over time, research questions have expanded to include terrestrial and aquatic species, communities and ecosystem dynamics. There are nine small experimental watersheds and 10 gaging stations in the HJA, including both reference and experimentally treated watersheds. Gaged watershed areas range from 8.5 to 6242 ha. All gaging stations record stage height, water conductivity, water temperature and above-stream air temperature. At nine of the gage sites, flow-proportional water samples are collected and composited over 3-week intervals for chemical analysis. Analysis of stream and precipitation chemistry began in 1968. Analytes include dissolved and particulate species of nitrogen and phosphorus, dissolved organic carbon, pH, specific conductance, suspended sediment, alkalinity, and major cations and anions. Supporting climate measurements began in the 1950s in association with the first small watershed experiments. Over time, and following the initiation of the Long Term Ecological Research (LTER) grant in 1980, infrastructure expanded to include a set of benchmark and secondary meteorological stations located in clearings spanning the elevation range within the Lookout Creek watershed, as well as a large number of forest understory temperature stations. Extensive metadata on sensor configurations, changes in methods over time, sensor accuracy and precision, and data quality control flags are associated with the HJA data.  相似文献   

Application of surface-wave tomography to mineral exploration: a case study from Siilinjärvi,Finland     

Federico Da Col  Myrto Papadopoulou  Emilia Koivisto  Łukasz Sito  Mikko Savolainen  Laura Valentina Socco 《Geophysical Prospecting》2020,68(1):254-269

In order to assess the feasibility and validity of surface-wave tomography as a tool for mineral exploration, we present an active seismic three-dimensional case study from the Siilinjärvi mine in Eastern Finland. The aim of the survey is to identify the formation carrying the mineralization in an area south of the main pit, which will be mined in the future. Before acquiring the data, we performed an accurate survey design to maximize data coverage and minimize the time for deployment and recollection of the equipment. We extract path-averaged Rayleigh-wave phase-velocity dispersion curves by means of a two-station method. We invert them using a computationally efficient tomographic code which does not require the computation of phase-velocity maps and inverts directly for one-dimensional S-wave velocity models. The retrieved velocities are in good agreement with the data from a borehole in the vicinity, and the pseudo three–dimensional S-wave velocity volume allows us to identify the geological contact between the formation hosting most of the mineralization and the surrounding rock. We conclude that the proposed method is a valid tool, given the small amount of equipment used and the acceptable amount of time required to process the data.  相似文献   

贵州夜郎湖表层水体地球化学昼夜变化及其影响因素     

王家录  任娟  王勇  李维杰  娄昭  陈佳 《热带地理》2020,40(2):335-345

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。  相似文献   

Kainsaz(CO3)陨石中两个富Al球粒的氧同位素组成特征与形成演化     

戴德求  包海梅  刘爽  尹锋 《岩石学报》2020,36(6):1850-1856

富Al球粒是原始球粒陨石中一种矿物岩石学特征介于富钙铝包体(CAIs)和镁铁质硅酸盐球粒之间的特殊集合体,所以常常认为富Al球粒在认识CAIs和镁铁质硅酸盐球粒形成演化过程中的相互联系具有特殊意义。然而,对富Al球粒的初始物质组成以及形成演化过程一直存在较多争议,而氧同位素组成研究能够对球粒演化和早期星云环境等提供重要的信息。在本文中我们报导了来自Kainsaz(1937年降落于俄罗斯,CO3型)碳质球粒陨石中的2个富Al球粒(编号K1-CH1和K2-CH2)的矿物岩石学和氧同位素组成特征。K1-CH1的矿物组成主要为橄榄石、低钙辉石和富钙长石,K2-CH2为橄榄石和富钙长石。2个球粒中的矿物均具有贫~(16)O同位素组成特征。K1-CH1中矿物的△~(17)O组成基本上位于2个区间:-11.1‰～-8.7‰和-3.9‰～0.4‰;而K2-CH2的△~(17)O介于-6.6‰～-0.6‰之间,且具有从中部至边部升高的趋势。矿物岩石学和氧同位素特征表明,这2个富Al球粒的初始物质组成为富CAIs和镁铁质硅酸盐。在球粒熔融结晶过程中,与贫~(16)O同位素组成(△~(17)O:-8.7‰～-7.8‰)的星云发生了氧同位素交换。球粒形成后,发生迁移进入陨石母体,在相对更贫~(16)O同位素组成(△~(17)O:-0.6‰～0.4‰)的母体中(流体参与)发生变质作用,并再次发生了氧同位素交换。  相似文献   

基于沉积过程的数字岩石建模方法研究          下载免费PDF全文

田志  肖立志  廖广志  董虎  田守嶒  宋先知 《地球物理学报》2019,62(1):248-259

本文提出模拟地层沉积及成岩过程的矿物沉积算法,建立数字岩石模型,并通过对比Micro-CT扫描图像和数值模型的局部孔隙度及平均渗流概率函数分布特征,评价建模的准确性.结果表明,由二维扫描提取的粒径信息作为输入参数,模拟矿物沉积过程建模得到的三维数字岩石模型,能够准确重构原始岩心的非均质性及渗流特性,成功应用于泥质砂岩、碳酸盐岩、页岩等存在多矿物或多尺度孔隙的数字岩石建模中.数字岩石物理是正在兴起的重要技术.数字岩石采用超高分辨率先进成像装备,采集和表征微纳尺度岩石结构,在岩石弹性、电性、核磁、渗流特性等数值计算中发挥重要作用.但是,由于三维直接成像在有限视域内难以表征足够的岩石非均质性,提取二维结构统计特征,利用统计或地质过程法重构具有代表性的三维岩石结构成为十分有价值的研究课题,而且,对业界大量存在的岩石薄片及电镜高清二维图像的深度开发应用也具有重要的现实意义.本文发展的新方法,复原沉积过程,较好地解决了孔隙尺度岩石物理定量研究中数值建模与理论计算的技术瓶颈.  相似文献   

龙马溪页岩弹性各向异性与矿物分布之间的关系探讨   总被引：1，自引：0，他引：1       下载免费PDF全文

伍宇明  兰恒星  黄为清 《地球物理学报》2020,63(5):1856-1866

岩石弹性各向异性特征是普遍存在的,但导致岩石弹性各向异性的原因复杂且仍然存在一定争议.本研究以龙马溪页岩为例,试图建立页岩弹性各向异性和矿物分布之间关系.研究使用无损超声波探测获取岩石弹性各向异性参数,并使用背散射技术获取岩石矿物分布特征.研究通过引进变异系数来描述矿物或孔裂隙在不同方向的差异性,并通过2个正交方向的变异系数建立微观异质性指标,用于表征微观尺度上矿物或孔裂隙在不同方向的差异程度.微观背散射图像显示,龙马溪组页岩主要由石英和伊利石构成,且这两种矿物和孔裂隙在X和Y面上都有定向排列特征.相应地,它们的变异系数在X面和Y面上均表现出随角度增大而降低的特征;而在Z面,石英、伊利石和孔裂隙变异系数变化不明显,这与Z面上矿物和孔裂隙无明显方向性的特点一致.无损超声波探测结果显示,波速在X和Y面上随角度增加而减小,这与主要矿物和孔裂隙变异系数变化趋势相同;而在Z面,波速变化不大,与主要矿物和孔裂隙变异系数变化不明显的特征一致.以上观测结果说明,宏观波速与矿物的微观变异系数明显相关,暗示岩石弹性各向异性与矿物分布直接相关.  相似文献   

Riparian land use and stream habitat regulate water quality     

《Limnologica》2020

Riparian land use is a key driver of stream ecosystem processes but its effects on water quality are still a matter of debate when proposing measures to improve freshwater quality. The aim of this study was to examine the influence of riparian land use on stream habitat and water chemistry, and to assess in what extent stream habitat also affects water quality. To that end, we selected eight reaches in the Ave River basin (northwestern Portugal) and compared longitudinal variations in water chemistry and stream habitat between reaches with different land use (urban, agricultural and natural), and between reaches with natural riparian areas and different habitats. Stream habitat was assessed using the Fluvial Functional Index, the HABSCORE, and the Riparian Forest Quality Index. Longitudinal variations in water chemistry were determined measuring differences in concentrations of ammonium, nitrate, phosphate and oxygen, and conductivity, pH and temperature between the downstream and the upstream ends of each reach. Nitrate concentration tended to decrease along reaches with more natural riparian areas and to increase along reaches with more urban and agricultural land uses. Longitudinal variations in water chemistry also differed between reaches with natural riparian areas, suggesting that water quality also depends on stream habitat. Moreover, longitudinal variation in water chemistry was proven a simple, useful and low-cost approach to assess the influence of land cover and stream habitat on water quality. Overall results demonstrated that both riparian land use and stream habitat influence water quality and that riparian forests are essential to reduce nutrient export to downstream ecosystems.  相似文献   

Multimodal water age distributions and the challenge of complex hydrological landscapes     

Nicolas B. Rodriguez  Paolo Benettin  Julian Klaus 《水文研究》2020,34(12):2707-2724

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Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step     

Gang Yang  Aaron Zimmerman  Nicole C. Hurtig  Svetoslav V. Georgiev  Vineet Goswami  Judith L. Hannah  Holly J. Stein 《Geostandards and Geoanalytical Research》2020,44(2):231-242

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.  相似文献   

Shenandoah Watershed Study-Virginia Trout Stream Sensitivity Study (SWAS-VTSSS): Stream water quality and hydrologic monitoring data for mid-Appalachian headwater streams     

Ami L. Riscassi  Todd M. Scanlon  Suzanne W. Maben  James N. Galloway 《水文研究》2021,35(4):e14164

The Shenandoah Watershed Study (established in 1979) and the Virginia Trout Stream Sensitivity Study (established in 1987) serve to increase understanding of hydrological and biogeochemical changes in western Virginia mountain streams that occur in response to acidic deposition and other ecosystem stressors. The SWAS-VTSSS program has evolved over its 40+ year history to consist of a temporally robust and spatially stratified monitoring framework. Currently stream water is sampled for water quality bi-hourly during high-flow events at three sites and weekly at four sites within Shenandoah National Park (SHEN), and quarterly at 72 sites and on an approximately decadal frequency at ~450 sites within the wider western Virginia Appalachian region. Stream water is evaluated for pH, acid neutralizing capacity (ANC), base cations (calcium, magnesium, sodium and potassium ion), acid anions (sulphate, nitrate and chloride), silica, ammonium, and conductivity with a subset of samples evaluated for monomeric aluminium and dissolved organic carbon. Hourly stream discharge (four sites) and in-situ measurements of conductivity, water and air temperature (three sites) are also measured within SHEN. Here we provide an overview and timeline of the SWAS-VTSSS stream water monitoring program, summarize the field and laboratory methods, describe the water chemistry and hydrologic data sets, and document major watershed disturbances that have occurred during the program history. Website links and instructions are provided to access the stream chemistry and time-series monitoring data in open-access federal databases. The purpose of this publication is to promote awareness of these unique, long-term data sets for wider use in catchment studies. The water chemistry and hydrologic data can be used to investigate a wide range of biogeochemical research questions and provide key inputs for models of these headwater stream ecosystems. SWAS-VTSSS is an ongoing program and quality assured data sets are uploaded to the databases annually.  相似文献